811 November.2010. In the first stage, the biodiesel is produced from raw cottonseed oil by the transesterification process and the second stage Al 2 O 3 nanoparticles are mixed in the diesel blends with 50 and 100 ppm by using ultrasonicator [5, 6, 8,9,10,11,12,13,14,15].. 2.1 Biodiesel Preparation. Biodiesel plays a major role in the energy sector due to its similar combustion properties with petroleum. L. A. Other physical properties are more similar between the two fuels, and their impacts are not clearly evident in the present study. These findings indicate that the biodiesels produced from WFO treated with different levels of adsorbents are less prone to oxidative rancidity. Likewise, the authors thank the Chemical Research Center (CIQ) of the Autonomous University of the State of Morelos for performing the gas chromatography-mass spectrometry analyses. were also . J. Zuiga-Daz, E. Reyes-Dorantes, A. Quinto-Hernandez et al., Biodiesel from Morelos rice: synthesis, oxidative stability, and corrosivity, Journal of Chemistry, vol. 22, no. Physico-chemical properties of biodiesel manufactured from waste frying PDF Study of Physical and Chemical Properties of Biodiesel from - ISCA B. O. V. A. Hemung and S. Pariwat, Chemical properties and fatty acid profile of lipids extracted from freshwater fish species. V. Kumar, P. Kant. The highest yields (86.45 and 87.80%) were observed for biodiesel samples produced from WFO treated with 2% Magnesol and 3% of RHA, respectively, followed by samples treated with 2 and 3% of DPSC or RHA. 52, no. A. Caldern, The oxidative stability of biodiesel and its impact on the deterioration of metallic and polymeric materials: a review, Journal of the Brazilian Chemical Society, vol. Emissions of hydrocarbons, CO, NOx, and particulate matter are similar to petrodiesel fuels, although can be reduced in some cases. In order to improve performance in the cold climate, additives are typically added to biodiesel. Lesson 2: Existing Fossil Fuel Technologies for Transportation, Lesson 4: Use of Biomass in Thermal Technologies, Lesson 5: Biomass Pyrolysis and Pretreatment, Lesson 7: Processing to Produce Ethanol and Butanol from Carbohydrates and Enzymes, Lesson 8: Thermochemical Methods to Produce Biofuels, 9.1 Terminology for Vegetable Oils and Animal Fats, 9.2 The Reaction of Biodiesel: Transesterification, 9.3 Various Processes Used to Make Biodiesel, 9.4 Biodiesel Properties and Specifications, Lesson 11: Economics of Biomass Production Ethanol, Butanol, and Biodiesel, Lesson 12: Additional Processes for Fuels from Biomass, Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License, Department of Energy and Mineral Engineering, Department of Materials Science and Engineering, Department of Meteorology and Atmospheric Science, Earth and Environmental Systems Institute, Earth and Mineral SciencesEnergy Institute, iMPS in Renewable Energy and Sustainability Policy Program Office, BA in Energy and Sustainability Policy Program Office, 2217 Earth and Engineering Sciences Building, University Park, Pennsylvania 16802. A blank was conducted where the total halogen content of the Hanus solution (25 ml) was determined by sodium thiosulfate solution without the addition of oil. 0 . Biodiesel is also a great solvent, better than petroleum-based diesel. 3rd Int. The density of the samples was determined by a mass over volume measurement at 40 C. Alternative Fuels Data Center: Biodiesel Fuel Basics - Energy Date palm seeds were washed with tap water, cut into small pieces, and dried at 150 C for 48 h. The dried product was treated with concentrated sulfuric acid (H2SO4 98%, Sp.gr.1.84) at a ratio of 2:1 (v/v). The Chemistry of Biodiesel | Biodiesel Project | Goshen College They react rapidly with oxygen and water vapour in the air when exposed. The AV of the starting material can play an important role on the %FAME of the final product [34]. sulphonic acid in liquid soap info@colegiobatistapenha.com.br. What's So Different about Biodiesel Fuel? - Penn State Extension It has a higher lubricity, low sulfur content, and low CO and hydrocarbon emissions. 2. TK9F#oNy8:yqcw~F?>w5OPeOJc_gj-nTm Gz" Gpya{[m~'1s3ZCxW9KmL3OK['Q- Z^}lMX/7_\n>EjutQjZ|J_q eo]G\]=y5mq9e,4YL[S3)4[3ToJ|IeZ+5UF[j%T8='kf1X1_mW'b@Q-LEZZ}]TKLzaPnR R_6]\v|zR_^]z. The FFA values after treatment dropped by 5075%. 89, no. The tested fuels were pure biodiesel (B100), 5% (v/v) ethanol biodiesel blend (E05B95), 10% (v/v) ethanol-biodiesel blend (E10B90), and 15% (v/v) ethanol-biodiesel blend (E15B85). Because of the higher cetane numbers of biodiesel, the engine running on biodiesel will have an easier time starting and have low idle noise. 9, pp. The highest efficiency for removing some unsaturated compounds was observed for biodiesel samples produced from WFO treated with 1% of RHA. 532534, 2014. Physical Properties of Bio-Diesel and Implications for Use of Bio The thermal, physical and chemical properties of biodiesel will influence on combustion flow and storage behaviours [1, 42, and 43]. These results are in good agreement with those of Domnguez et al [28] and Ullah et al [29], who reported that pure biodiesel possesses an RI in the range of 1.45. This study consists of two parts, first one is biodiesel characterization and the second one is testing in the engine. Figure 9.15: Conversion of glycerides to biodiesel showing intermediates. S. Piazzini, E. Lori, L. Favilli et al., A tropical fish community in thermal waters of Southern Tuscany, Biological Invasions, vol. Experimental data and prediction of the physical and chemical The samples used are conventional diesel (STD), B80, B90 and B100 were stored at ambient temperature (24 C) for nine week. GC shows that thumba oil . O2 kg1. Its kinematic viscosity is in the range of 3.6 to 5.7 at 37.8 C. F. F. P. Santos, J. Q. Malveira, M. G. A. Cruz, and F. Fan, Production of biodiesel by ultrasound assisted esterification of Oreochromis niloticus oil, Fuel, vol. physical and chemical properties of heavy fuel oil Most petro-diesel fuels have a cetane number of 40-50 and meet the ASTM specification for ASTM D975. 228238, 2013. This usually is the first step in the oxidative degradation pathway of biodiesel [38]. However, the purification process with 1% of RHA caused significant decreases in RIs. According to the results, the biodiesel yield obtained was 90.71% (m/m), the acid value and the kinetic viscosity reported are lower than those observed for other fuels derived from fish waste, and the flash point and density are within the ranges of biodiesel obtained with other fish species. . 123132, 1996. There are three main types of fatty acids that can be present in a triglyceride that is saturated (Cn:0), monounsaturated (Cn:1), or polyunsaturated with two or three double bonds (Cn:2,3). The PV determination measures the presence of oxidative moieties (i.e., the portion of a molecule bearing characteristic oxidative properties) in a sample. M. T. Lisboa, C. D. Clasen, D. C. De Sousa Vellar et al., An easy and fast procedure for the determination of Ca, Cu, Fe, Mn, Mg, Na, K and Si in biodiesel by ICP OES using emulsification as sample preparation strategy, Journal of the Brazilian Chemical Society, vol. 4853, 2008. The fatty acid compositions of the biodiesel produced from WFO and WFO treated with different levels of adsorbents are summarized in table table1.1. hN0_,8#!Z@H=&hS3?)*&3f3&4b0]k The IV was determined using the Hanus method, as described in AOAC (920.158) [20]. It really depends on the location; for instance, if using biodiesel in the upper Midwest, there could be problems in the winter. 24, no. According to Knothe et al [49], high CNs were observed for esters of saturated fatty acids such as palmitic (C16:0) and stearic (C18:0) acids. physical and chemical properties of heavy fuel oil The functionality is limited to basic scrolling. Fatty acid composition and . 11, no. 12, p. 1316, 2016. . 249255, 2017. In accordance with the US Standard Specification for Biodiesel (ASTM 6751), biodiesel is defined as a fuel comprised of mono-alkyl esters of long-chain fatty acids derived from vegetable oils or animal fats [5]. Energy from Biomass and Waste; Venice, Italy. The purification process with various levels of adsorbent caused significant (p 0.05) decreases in PVs. We are experimenting with display styles that make it easier to read articles in PMC. Please let us know here why this post is inappropriate. 5, p. 1583, 2018. Country. Yield of biodiesel produced from WFO and WFO treated with various levels of adsorbents. The adsorbent Magnesol XL (a hydrous, white, amorphous, and odorless synthetic magnesium silicate) was obtained from the Magnesol Product Division, Reagent Chemical and Research, Inc., in Houston, TX, USA. A. These values reveal that treated samples are more resistant to oxidation than those without purification treatment. Due to its different properties, biodiesel will cause some changes in the engine performance and emissions including lower power and higher oxides of nitrogen. Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration. Biodiesel and its blends B20 and B50 were prepared in two stages. The data were analyzed by analysis of variance according to the procedures outlined by Gomez and Gomez [24]. The IVs of the obtained biodiesel ranged from 44.1854.30 g I2/100 g oil. The SVs of biodiesel produced from WFO and WFO treated with different levels of adsorbents are shown in figure figure6.6. 205214, 2018. Date palm seed carbon (DPSC) was prepared according the method described by El Nemr et al [19]. This makes it good to blend with diesel from petroleum to be able to achieve the required specifications for ultra-low sulfur diesel, because ultra-low sulfur diesel has poor lubricity. These values were significantly (p 0.05) lower than the maximum value approved by both EN 14214 [33] and ASTM D6751 [5] standard fuels. 9, pp. The biodiesels from the transesterification reaction were characterized for their physical and chemical properties. Vacuum filtration facilitated the flow of oil through the filter paper. Values followed by the same letter (, Acid value of biodiesel produced from WFO and WFO treated with various levels of adsorbents. 5, pp. General physical properties of Group 1 elements: Alkali metals are grey solids with shiny silvery surfaces when freshly cut. A. Pollardo, H. Lee, D. Lee et al., Solvent effect on the enzymatic production of biodiesel from waste animal fat, Journal of Cleaner Production, vol. Sugar cane bagasse (SCB) was obtained from the Hawamdiah sugar refinery company, El-Hawamdiah, Egypt. Physical and chemical properties of biodiesel and light diesel mixed Resources. Influence of Physical and Chemical Properties of Two Biodiesel Fuels on P. M. A. Klaic, A. M. Nunes, A. D. Moreira et al., Determination of Na, K, Ca and Mg in xanthan gum: sample treatment by acid digestion, Carbohydrate Polymers, vol. Lesson 1: Why Alternative Fuels from Biomass? The unpurified WFO was vacuum filtered through a Whatman No. Values followed by the same letter (a, b, c, d, e) are not significantly different (p < Density is an important fuel property, because injection systems, pumps, and injectors must deliver an amount of fuel precisely adjusted to provide proper combustion [30]. The properties of the triglyceride and the biodiesel fuel are determined by the amounts of each fatty acid that are present in the molecules. Refractive index at 40 C of biodiesel produced from WFO and WFO treated with various levels of adsorbents. 2015 Jun; 16(3): 034602. adsorbents, filter, transesterification, biodiesel characteristics, waste frying oil, COX value, Refractive index at 40 C of biodiesel produced from WFO and WFO treated with various levels of adsorbents. The most prominent fatty acids in the produced biodiesel were C 16:0 palmitic acid (43.5150.72%) and C 18:1 oleic (cis-9-octadecenoic) acid (40.4150.10%). L. T. Thanh, K. Okitsu, Y. Sadanaga et al., A new co-solvent method for the green production of biodiesel fuel-optimization and practical application, Fuel, vol. Fatty acid composition of biodiesel produced from WFO and WFO treated with various levels of adsorbents. The PV was determined according to the AOAC method (965.33) [20]. Charoenchaitrakool M. and Thienmethangkoon J. ASTM D664-664-9 11a. 8, no. J. F. Costa, M. F. Almeida, M. C. M. Alvim-Ferraz, and J. M. Dias, Biodiesel production using oil from fish canning industry wastes, Energy Conversion and Management, vol. PDF Properties of Biodiesel and Other Bi i F lBiogenic Fuels - NIST The authors declare that they have no conflicts of interest. 2015, Article ID 630168, 9 pages, 2015. PV is expressed as the milliequivalent of the O2 kg1 sample. Results indicated that the content of WFOs of the blends influenced the physical and chemical properties of the biofuel, but did not influence the rheological behavior of . Influence of physical and chemical properties of biodiesel fuels on 60 0 obj <> endobj Data are expressed as mean standard deviation (SD) of three replicates. Generating an ePub file may take a long time, please be patient. The PVs of the obtained biodiesel varied from 1.253.96 meq. 87, no. The physical and chemical properties of biodiesel are largely dictated by the specific compositional profile of the FAME material. I.-C. Kuan, W.-C. Kao, C.-L. Chen, and C.-Y. One is a study of the effects of biodiesel fuel physical properties on injection characteristics and spray behaviour. Values are means of three determinations. physical and chemical properties of fuel 1 min. We have evaluated the efficiency of sugar cane bagasse ash (SCBA), date palm seed carbon (DPSC), and rice husk ash (RHA) as natural adsorbents and compared them with the synthetic adsorbent Magnesol XL for improving the quality of waste frying oil (WFO) and for the impact on the physicochemical properties of the obtained biodiesel. 202, pp. These include viscosity, cloud point, pour point and cold filter plugging point. The purpose of this study is to examine the influence of biodiesel (BD) fuel properties on different characteristics of the engine and to compare with the baseline petroleum diesel (PD) fuel. Flash point. Values followed by the same letter (a, b, c, d, e) are not significantly different (p < 0.05) by Duncans multiple range test. Furthermore, biodiesel is sometimes superior to petroleum diesel with improved physical and chemical properties, such as a higher flash point, higher cetane number, ultralow sulfur content, better lubricity, improved biodegradability, and a smaller carbon footprint [13]. The oven temperature was programmed from 150170 C at a rate of 10 min, then raised to 192 C at a rate of 5 C min1, kept at this temperature for 5 min, and then raised again to 220 C at a rate of 10 C min1and kept at this temperature for 3 min. % It is best to avoid copper, brass, lead, tin, and zinc containers. Biodiesel produced from WFO without purification treatments had the highest acid value at 0.41. The site editor may also be contacted with questions or comments about this Open Educational Resource. 1. In this respect, there are various methods that can be used to remove these products, such as filtration through special membranes [11, 12] and by using different adsorbent materials, including both natural and synthetic adsorbents. Gas chromatography-mass spectrometry of Amazon sailfin catfish biodiesel. Properties of biodiesel. The FAMEs were identified using a gas chromatograph equipped with a DB-23 capillary column (60 m, 0.32 mm ID, 0.25 m film thickness) and a flame ionization detector. A. Levin, P. H. Phuong, and D. S. Pavlov, Discovery of the Amazon sailfin catfish Pterygoplichthys pardalis (castelnau, 1855) (Teleostei: Loricariidae) in Vietnam, Journal of Applied Ichthyology, vol. ta je to Sungazing; Benefiti i postupak sangejzinga i uzemljavanja; Miroslav Kis- Dnevnik SG; Saveti za brze rezultate A blank was performed where the same volume of alcoholic potassium hydroxide solution without oil was treated similarly as in the experiment. The properties of biodiesel which are acid value, flash point . 76, pp. Values are means of three determinations. Saponification value (SV) was determined according to the AOAC method (920.160) [20]. Moreover, when the biodiesel temperature is near the cloud point, a cloudy state appears, and the RI changes; hence, it is a significant parameter to evaluate the state of a biodiesel. 65, pp. 102, pp. R. S. Amais, E. E. Garcia, M. R. Monteiro, and J. alcohol fuels, biodiesel has a lower energy content and different physical properties than diesel fuels (Tat and Van Gerpen, 1999; Tat and Van Gerpen, 2000a; and Tat et al., 2000b). PDF Biodiesel Quality, Standards and Properties Amazon sailfin catfish (<i>Pterygoplichthys pardalis</i>) is considered one of the greatest threats to the biodiversity of continental aquatic systems, causing serious economic and environmental problems in the regions. en ecosistemas Mxico, pp. The injector and the detector temperatures were 230 C and 250 C, respectively. These values reveal that treated samples are more resistant to oxidation than those without purification treatment. 742748, 2013. The authors declare that there is no conflict of interest. This allows to significantly reduce the environmental impact of this species in the subject geographical area. The topic of biodiesel fuel has been receiving a great deal of interest recently, and both . C. Y. Lin and R. J. Li, Fuel properties of biodiesel produced from the crude fish oil from the soapstock of marine fish, Fuel Processing Technology, vol. Some terminology to be aware of: 1) bound glycerol is glycerol that has not been completely separated from the glyceride and is the sum of tri-, di-, and mono-glycerides and 2) total glycerol combines the bound glycerol with the free glycerol. kg1, a value lower than that established in the European standard (Table 2). 455463, 2017. 166, pp. The physical and chemical properties of biofuel produced were evaluated under the . V. F. De Almeida, P. J. Garca-Moreno, A. Guadix, and E. M. Guadix, Biodiesel production from mixtures of waste fish oil, palm oil and waste frying oil: optimization of fuel properties, Fuel Processing Technology, vol. 18951900, 2011. The highest yields (86.45 and 87.80%) were observed for biodiesel samples produced from WFO treated with 2% Magnesol and 3% of RHA, respectively, followed by samples treated with 2 and 3% of DPSC or RHA. The high FFA content (>1%; w:w) will cause soap formation, and the separation of products will be exceedingly difficult; as a result, it has a low yield of biodiesel product [36]. F. Anguebes-Franseschi, M. Abatal, A. Bassam et al., Esterification optimization of crude African palm olein using response surface methodology and heterogeneous acid catalysis, Energies, vol. Biodiesel Characterization (Physico-Chemical Properties of Biodiesel A Samat, M. N. Shukor, A. G. Mazlan et al., Length-weight relationship and condition factor of Pterygoplichthys pardalis (pisces: Loricariidae) in Malaysia Peninsula, Research Journal of Fisheries and Hydrobiology, vol. Values followed by the same letter (, Peroxide value of biodiesel produced from WFO and WFO treated with various levels of adsorbents. Values are means of three determinations. 42, pp. It depends on the normal temperature of the climate as to whether the fuel can be used or blended with petrodiesel. Assessment of physical, chemical, and tribological properties of Jurisdiction. Vegetable oil, like biodiesel, belongs to a category of compounds called esters. physical and chemical properties of heavy fuel oilhandel flute sonata in g major accompaniment. In this work, the production of biodiesel from Amazon sailfin catfish biomass oil is studied. 41 filter paper (Whatman International Ltd, Maidstone, UK). Another issue is cold weather properties for biodiesel. The efficiency of the adsorbents under study in improving the physical and chemical properties of biodiesel samples produced from WFO was nearly the same. In addition, the application of biodiesel is limited due to its poor cold weather properties. In this study, biodiesels from five different feedstocks . However, it is advisable to add an antioxidant agent to the manufactured biodiesel derived from fish to improve its useful life, due to the presence of high concentrations of polyunsaturated methyl esters. In fact, for oil with high FFA levels, the first esterification cannot meet the alkali catalyzed reaction conditions, which requires a second esterification in order to reduce acid value to less than 2 mg KOH g1 oil [44]. Oxidation products, which may include gums, acids, and peroxides, aredetrimental to the performance of diesel engines [25]. A. Prez, A. D. P. Peralta, H. Guillen, and L. E. ngel, El pez diablo (Pterygoplichthys spp.) Country/Area . Only the change of glycerol by methanol is produced. The results of the COX values for the biodiesels under study are shown in table table1.1. Values are means of three determinations. Physico-chemical properties are the intrinsic physical and chemical characteristics of a substance. standards. 5866, 2015. The IVs of biodiesel produced from WFO and WFO treated with different levels of adsorbents are shown in figure figure7.7. 38, no. Titration was continued after adding a few drops of starch as an indicator until the blue color had entirely disappeared. Least significant difference (LSD) at 5% level = 0.081. Least significant difference (LSD) at 5% level = 0.0008. Density of biodiesel produced from WFO and WFO treated with various levels of adsorbents. Refractive index at 40 C of biodiesel produced from WFO and WFO treated with various levels of adsorbents. 17, pp. Values are means of three determinations. 154157, 2015. Castor oil has long been used commercially as a highly renewable resource for the chemical industry.1,2 It is a vegetable oil obtained by pressing the seeds of the castor oil plant (Ricinus communis L.) that is mainly cultivated in Africa, South America, and India.3,4 Major castor oil-producing countries include Brazil, China, and India. 5, pp. Thus, it is a useful parameter for standardization of the product [27]. However, the lowest values (0.440.73) were observed for biodiesel samples produced from WFO treated with different levels of adsorbent. In this work, production of biodiesel from blends of virgin castor oil (VCO) and waste frying oil (WFO) was studied. 2, pp. Moreover, a mineral analysis by atomic absorption showed the absence of heavy metals Cd, Ni, and Pb, as well as low concentrations of Ni, Fe, Cu, and Zn, demonstrating that the quality of the fuel is not compromised. Physico-chemical properties of biodiesel manufactured from waste frying oil using domestic adsorbents, National Institute for Materials Science and Taylor & Francis, Department of Biochemistry, Faculty of Agriculture, Cairo University, 12613, Giza, Egypt. The wastes can be used if they are purified; used frying oil is purified by removing its free fatty acids (FFAs) by magnesium oxide adsorption [10]. Copyright 2019 F. Anguebes-Franseschi et al. %PDF-1.4 4, pp. Glycerol content in biodiesel must be as low as possible, as ASTM standards state. Concentration of metals found in the Amazon sailfin catfish biodiesel.
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